Superbti
is a professional company supplying high performance titanium bars, wire,
plates, forgings, tubes and fasteners.
From
the heat permeability expansion, electroplating, such as vacuum coating
processing technology, the traditional surface strengthening, wear-resisting
development to the present stage to plasma permeability, the application of ion
beam, electron beam, laser beam marked by modern surface treatment technology,
such as surface nitriding, gas nitriding, plasma nitriding, surface seepage
element alloying, laser cladding, etc. At present, the titanium and titanium
alloy surface strengthening technology is moving toward a variety of surface
technology comprehensive application and research of multilayer composite
coatings preparation direction.
Titanium
alloy carburizing TiC phase is generated on the surface, has the very high
hardness. But the adhesion strength of the TiC layer and substrate is very
poor, interfere with the actual use. High temperature can make titanium carbide
grain growth speed:
The
sintering temperature. Titanium carbide high manganese steel bonded carbide
final sintering temperature generally take 1420 ℃ more
appropriate. The sintering temperature is unfavorable and exorbitant. Even make
binding phase liquid metal loss and adjacency, aggregation and grew up in the
hard phase, fractured formation source. This is the analysis of grain size of
hard phase in front of the bonding between the phase changes little. Sintering
temperature, of course, also cannot too low, otherwise it will make the alloy
owe to burn, especially the degumming, reduction and liquid phase sintering in
three stages.
During
sintering, the heating speed. This kind of alloy sintering temperature when
heating should not be fast to strictly control the heating rate and holding time.
Because in the low temperature degumming phase, compact release stress and
forming process of volatile, if warming faster, by forming agent and steam to
volatilize and liquefaction, make compact burst or micro crack phenomenon;
Above 900 ℃ reduction stage, to make compact have
enough time to take off all use the raw material powder (such as Mn2Fe
intermediate alloy) in volatiles and oxygen; Into the liquid phase sintering
stage, also want to heat up a little slower talents make compact fully
alloying.
Titanium
will at high temperatures and oxygen, nitrogen and other gases, cause
hardening, high temperature (800-900 degrees) nitride processing, make its
surface vickers hardness up to more than 700;By surfacing welding, with the
right amount in the argon gas nitrogen or oxygen, make its surface hardness can
be improved 2-3 times; Through ion plating, make its surface generates a
titanium nitride layer, the thickness of the 5 microns, vickers hardness on the
surface of a whopping 16000-20000;Chrome plating, etc. When nitriding may form
a variety of different area, if you don't high oxygen content, form the outer
zone of titanium nitride, with golden color and hardness of 14000-14000 MPa,
but this kind of titanium nitride layer is fu due to the low temperature or
nitride and high temperature heated (annealing), nitrogen is completely
dissolved into the titanium metal on the surface of the solid solution,
titanium intensified layer no longer increases or disappear in a heat treatment
process, therefore, the discovery of titanium nitride layer when ti solid
solution have dissolved into nitrogen the layer with high hardness, but the
core hardness decrease. When using nitriding of ammonia, due to the effect of
hydrogen permeation and additional organizational change. Titanium nitride hard
and conductive titanium nitride heat generated more than all of the titanium
oxide. Therefore also must pay attention to, under the condition of complete
removal of oxygen for nitriding processing. Titanium surface will react with
nitrogen in time according to the parabola law. Therefore, nitriding rate
increased with the increase of nitriding time reduction. Because nitrogen out
of the titanium nitride layer diffusion velocity is less than the following Ti
solid solution of the diffusion velocity of body, and impossible to form a
thick nitride layer, nitrogen or ammonia must have a high purity. Because
oxygen not only hinder the formation of the nitride layer, but also can produce
surface layer under the condition of relatively high temperature to remove
oxide skin, the content of moisture (humidity) must be at least to such a
degree, even to melting point.
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